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Skip to Search Results- 1Amundarain, Jesus
- 1Ansari, Nesma Nasir
- 1Berahman, Behnam
- 1Cardozo, Samuel D.
- 1Carvalho do Prado, Glaucia H
- 1Dechaine, Greg Paul
- 6Xu, Zhenghe (Chemical and Materials Engineering)
- 3Gupta, Rajender (Chemical and Materials Engineering)
- 3Liu, Qingxia (Chemical and Materials Engineering)
- 3Zeng, Hongbo (Chemical and Materials Engineering)
- 2Gray, Murray R. (Chemical and Materials Engineering)
- 2Thundat, Thomas (Chemical and Materials Engineering)
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Fall 2009
In this study, we describe the use of different silica materials to separate vanadium compounds from Asphaltenes. We used high performance flash chromatography separation method to separate asphaltenes at different solvent strengths on sea sand. The separation conditions were optimized for flow...
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Spring 2010
Most crude oils contain traces of vanadyl porphyrins within their asphaltene fraction. Although these metals are only present in trace quantities, they have a significant detrimental impact on crude oil processing units; therefore, their selective removal is highly desirable. The current work...
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Characterization of Athabasca asphaltenes separated physically and chemically using small-angle X-ray scattering
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Athabasca asphaltenes were characterized using small-angle X-ray scattering (SAXS) with synchrotron radiation. Two methods were used to separate asphaltenes from Athabasca bitumen. Conventional chemical separation by precipitation with n-pentane, and physical separation realized by passing...
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Spring 2011
A Surface Forces Apparatus (SFA) was used in this study to investigate the fundamental surface forces in oil sand processing research. Asphaltene coated surfaces were chosen as the research topic due to the critical role of asphaltenes in oil sands processing, from bitumen extraction, froth...
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Fall 2011
Large polycyclic aromatic nitrogen containing asphaltene model compounds, with molecular weights from 535 to 702 g/mol, were catalytically hydrogenated and hydrodenitrogenated in the presence of a commercial NiMo/γAl2O3 catalyst in a stainless steel batch reactor at 370 °C and 17.9 MPa total...
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Fall 2011
The removal of solid particulates from crude oils and hydrocarbon streams is a common challenge in refining. Finding a method for efficient removal of the suspended solids in the oil streams is the main objective of this work. Paraffinic and aqueous treatment and the combination of these two...
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A Molecular Dynamics Study of the Dissolution of Asphaltene Model Compounds in Supercritical Fluids
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The demand for a new solvent to treat oilsands was behind the purpose of this project; molecular dynamics simulation was used in this study. Supercritical water, supercritical carbon dioxide and other selected organic solvents in their supercritical state were studied. Meso-tetraphenyl porphyrin...
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Fall 2011
Liquid crystalline domains were observed in fractions of heavy petroleum. Through a combination of polarized light microscopy and Photoacoustic Infrared Spectroscopy, liquid crystals were shown to form on the exterior surface of their parent materials. Analysis of materials using Differential...
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A Preliminary Study on Pyrolysis and Gasification of Asphaltenes and Coal-Asphaltenes Slurry in Entrained Flow Reactor
DownloadFall 2012
The aim of this work is to study pyrolysis of coal-asphaltenes slurry in an atmospheric entrained flow reactor. Athabasca asphaltenes and Genesee coal, both from Alberta in Canada, were selected as the feedstock. Char characteristics and the structure of asphaltenes and slurry chars including...
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Fall 2012
This thesis explored the properties of asphaltene nano-aggregates in crude oil and toluene based solutions and fouling at process furnace temperatures, and the links between these two phenomena. The link between stability of asphaltenes at ambient conditions and fouling at the conditions of a...