Journal Articles (Chemistry)
Items in this Collection
- 69Klassen, John S.
- 54Serpe, Michael J.
- 52Kitova, Elena N.
- 17Gao, Yongfeng
- 13Islam, Molla R.
- 13Loppnow, Glen R.
- 20Electrospray ionization mass spectrometry
- 12Stimuli-Responsive Polymers
- 11Photonic Materials
A 77‐K cold stage has been developed for spectroscopic measurements in an optical microscope. This stage eliminates fogging of the optical windows observed in an earlier design by adding vacuum jackets around the liquid nitrogen transfer lines and by maximizing the sample‐to‐environment distance...
A Convergent Route to Enantiomers of the Bicyclic Monosaccharide Bradyrhizose Leads to Insight into the Bioactivity of an Immunologically Silent LipopolysaccharideDownload
The synthesis of bradyrhizose, the monosaccharide component of the lipopolysaccharide O-antigen of the nitrogen-fixing bacteria Bradyrhizobium sp. BTAi1 and sp. ORS278, has been achieved in 25 steps in an overall yield of 6% using myo-inositol and ethyl propiolate as the starting materials. The...
The human genome is susceptible to change; base mismatches can arise from damaged DNA, replication errors, and spontaneous mutation, and have the potential to cause apoptosis, carcinogenesis, and mutagenesis. Many techniques have been developed for DNA mismatch detection, but many of these...
A novel four nuclear magnetic resonance (NMR)-tube holder is described for quantitative Raman and resonance Raman spectroscopy. This cell has advantages over other divided cell designs in producing high precision quantitation and eliminating off-axis errors. Raman spectra were obtained for both...
A Route to Polyprenol Pyrophosphate-Based Probes of O- Polysaccharide Biosynthesis in Klebsiella pneumoniae O2aDownload
An approach for the assembly of polyprenol pyrophosphate-based probes of O-polysaccharide biosynthesis in Klebsiella pneumoniae serotype O2a is described. This convergent route features high yielding, diastereoselective glycosylations and the late stage installation of the polyprenol...
Absorption of UV light by nucleic acids can result in the formation of molecular lesions in DNA and RNA, leading to mutagenesis, carcinogenesis, and cell death. In this work, hairpin oligonucleotide probes, which have previously been shown to be selective for DNA damage, are used. The hypochromic...
A Standardized Method for the Calibration of Thermodynamic Data for the Prediction of Gas Chromatographic Retention Times
A Standardized Method for the Calibration of Thermodynamic Data for the Prediction of Gas Chromatographic Retention TimesDownload
A new method for normalizing thermodynamic data to be used in the prediction of analyte retention times is presented. The method allows thermodynamic data collected on one column to be used in making predictions across columns of the same stationary phase but with varying geometries. This...
Optical devices were fabricated by sandwiching a “monolithic” poly(N-isopropylacrylamide-co-N-(3-aminopropyl) methacrylamide hydrochloride) (pNIPAm-co-APMAH) microgel layer between two semitransparent Au layers. These devices, referred to as etalons, exhibit characteristic multipeak reflectance...
A versatile surface modification technique was developed to yield poly(N-isopropylacrylamide) (pNIPAm) microgel-based thin films on a variety of substrates, e.g., metals, nonmetals, and polymers. Because the chemistry, and hence functionality and responsivity, of the pNIPAm-based microgels is...
A series of Ir1–xCux (x = 0–0.5) hydrous oxide nanoparticles (HO-np) were prepared simply by stirring solutions of IrCl3 hydrate and CuCl2 hydrate in aqueous KOH under air. Their water oxidation activities were measured in 0.1 M HClO4. The Ir0.89Cu0.11 HO-np was the most active catalyst in the...