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[(tert-Butyldimethylsilyl)oxy]methanethiol and [(tert-Butyldiphenylsilyl)oxy]- methanethiol—Nucleophilic Protected H2S Equivalents
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- Author(s) / Creator(s)
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[(tert-Butyldimethylsilyl)oxy]methanethiol [HSCH2OSiMe2Bu-t] is a nucleophilic reagent for
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introduction of a protected bivalent sulfur; this reagent is complementary to the electrophilic reagent p-MeC6H4SO2SCH2OSiMe2Bu-t. The thiol is prepared by the action of HSLi on tert-butyl(chloromethoxy)dimethysilane [ClCH2OSiMe2Bu-t] and it reacts with alkyl bromides to give protected thiols. -
- Date created
- 2015-01-01
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- Subjects / Keywords
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- Type of Item
- Article (Draft / Submitted)