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Spring 2011
Third-generation optoelectronics, which utilize nanoscale materials, have received a considerable amount of attention in the chemical sciences and are poised to make a large impact in both fundamental research and real-world application. In order to make a contribution to the field, this thesis...
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Aquatic nanotoxicity testing: Insights at the biochemical, cellular, and whole animal levels
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Aquatic organisms are susceptible to waterborne nanoparticles and there is only limited understanding of the mechanisms by which these emerging contaminants affect biological processes. The unique properties of nanomaterials necessitate evaluation of standard toxicity testing techniques to...
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Spring 2019
Synthetic oligodeoxynucleotides containing unmethylated CpG motifs (CpG ODNs) are powerful stimulators of innate and adaptive immune responses, exerting their activity through the interaction with endolysosomal Toll-like receptor 9 (TLR9) expressed by antigen presenting cells (APCs). The strong...
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Cell-electronic Sensing of Cellular Responses and Toxicity Induced by Nanoparticles and Arsenic Species
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We demonstrate the development of a real-time cell analysis (RTCA) platform for studying nanoparticle- and arsenic-induced cytotoxicity with potential applications to risk assessment, environmental toxicity monitoring, and drug development. RTCA is an impedance-based in vitro detection system...
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Spring 2011
Selective ring opening of naphthenic molecules is a preferred reaction to increase cetane number of fuels, and it should result in products with no loss in molecular weight and longer alkyl side chains. Benzocyclopentane (indan) ring opening was studied under hydrogen atmospheric pressure at 609...
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Synthesis and screening of heterogeneous multimetallic nanoparticle catalysts for mono-, poly- and heteroaromatic hydrogenation activity under mild conditions
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Nanoparticle catalysts have shown to be advantageous over traditional catalysts for many reasons and active for a wide variety of reactions. This thesis describes an approach for the synthesis and screening of heterogeneous multimetallic nanoparticle catalysts for aromatic hydrogenation activity...
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Protein Separation with Self-Assembled Nanoparticle Beds: Mechanism and Separation Performance
DownloadSpring 2016
This thesis reports the separation behavior of SDS-protein complexes in colloidal self-assembled (CSA) nanoparticle beds, and the processes of stabilization of CSA beds for high voltage separation. First, the variation of electrophoretic mobility with molecular weight (6.5-66 kDa) of SDS-protein...
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Earth-Abundant Transition Metal Hydride Complexes for Dehydrocoupling and Hydrosilylation Catalysis
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The research presented in this thesis details the synthesis of transition metal hydride complexes, with the focus on utilising these complexes for (a) the dehydrocoupling of amine-borane adducts, and (b) the hydrosilylation and hydroboration of unsaturated organic moieties. In both instances,...
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Fall 2019
Carboxylic acids are a ubiquitous class of molecules in the field of organic chemistry and represent versatile building blocks in synthetic chemistry. Methods that enable the formation of new carbon–carbon or carbon–heteroatom bonds from carboxylic acids via the extrusion of carbon dioxide can...
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Spring 2021
Emulsion flooding and heavy oil recovery by in-situ emulsion formation have been reported to show great potential in enhancing heavy oil recovery. Emulsion stability is the key issue controlling the success of this process; conventionally, surfactants were used to facilitate emulsification and...