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Characterization of magnetic nanoparticles as contrast agents and their application for quantitative magnetic susceptibility monitoring of the waterflooding of heavy oil in real time
DownloadSpring 2018
Waterflooding is one enhanced oil recovery process used in heavy oil reservoirs such as at Cold Lake in North-Eastern Alberta. However, little has been published in terms of imaging heavy oil waterfloods, mainly due to the similar densities of water and heavy oil, which makes it difficult to...
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Characterization of Particulate Matter Morphology and Volatility for Two Direct-Injection Engines
DownloadFall 2015
Particulate matter emitted from two direct injection engines has been characterized by morphology, volatility, mass-mobility exponent, effective density, and size distribution using tandem measurements from a centrifugal particle mass analyzer (CPMA) and differential mobility analyzers (DMA). The...
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Chiral Transition Metal Complexes under Resonance: Mechanism of a New Form of Chiral Raman Spectroscopy
DownloadFall 2023
My PhD thesis primarily focuses on exploring chiroptical events and signatures of chiral transition metal complexes when they are under (near) resonance conditions. To achieve this goal, multiple chiroptical spectroscopic techniques were utilized, aided by theoretical calculations. These...
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Fall 2018
General Purpose computing with Graphics Processing Units (GPGPU) is a method of com-putation that allows for calculations to be performed in parallel. Graphics Processing Units(GPU) allow a single basic computer to perform as well as a super computer cluster composedof only Central Processing...
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Computational Investigation of Electrical Conductivities and Magnetism of Phosphonate Metal-Organic Frameworks and Frontier Orbital Gaps, Structure, and Proton Transfer Mechanisms in Phosphonate Hydrogen-Bonded Organic Frameworks
DownloadSpring 2024
The study of metal-organic frameworks (MOFs) and hydrogen-bonded organic frameworks (HOFs) has gained much interest over the last decade. MOFs and HOFs are constructed through the self-assembly of organic building units and metals (in the case of MOFs), giving rise to a diverse range of...
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Fall 2012
Dendritic cells (DCs) play a central role in shaping antigen-specific immune response. Antibody-mediated antigen targeting to DC-specific surface receptors is a promising approach to enhance vaccine efficacy. The objective of this thesis was to develop DC-targeted nanoparticulate formulations for...
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Dependence of the Interfacial Adhesion between Two Different Types of Material on their Electron Work Function and Electrical Conductivity
DownloadFall 2021
We observed and investigated a novel interfacial phenomenon related to the dependence of interfacial bonding or adhesive force (Fad) between two substances on the difference in their Electron Work Functions (EWF) or Δφ, and developed a model to quantify such a dependence. First, using...
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Development and Application of Protected Amino Acids for the Installation of Stable Post-translational Modifications Using Solid-Phase Peptide Synthesis
DownloadFall 2022
This thesis describes the synthesis of non-canonical amino acid building blocks and their use in solid-phase peptide synthesis (SPPS) to explore peptidic drug analogues based on natural products. We replaced sensitive functionalities found in the structure of naturally produced peptides with...
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Fall 2019
Carboxylic acids are a ubiquitous class of molecules in the field of organic chemistry and represent versatile building blocks in synthetic chemistry. Methods that enable the formation of new carbon–carbon or carbon–heteroatom bonds from carboxylic acids via the extrusion of carbon dioxide can...
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Spring 2012
The study of heterobimetallic complexes (having two different metal atoms) involves combining the unique properties of each metal, which can give rise to interesting contrasts in reactivity compared to either metal alone. With two different metals incorporated into one complex, a more diverse...