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Spring 2021
A thorough overview of esters and their reductions is presented. A large focus was placed on reductions via homogeneous catalytic hydrogenation. Although several ester hydrogenation systems have been developed, the production of highly enantioenriched alcohols has generally relied upon the usage...
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Fall 2015
Oil sands found in Athabasca and Cold Lake regions of Northern Alberta form Canada’s primary source of energy reserves. Asphaltenes, a significant part of bitumen is often considered to be the least valuable component of crude oil due to various factors such as difficulty in transporting and...
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Fall 2015
Bimetallicity is known to provide synergistic effects and improve catalytic performance of monometallic counterparts in a variety of applications. Conventional impregnation methods for supported catalyst preparation do not allow for the control of bimetallic nanoparticle structure or size, which...
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Dynamic Demulsification Mechanism of Asphaltene-Stabilized Water-in-Oil Emulsions by Ethylcellulose
DownloadFall 2015
In previous studies, nontoxic and biodegradable ethylcellulose (EC) was shown to be capable of breaking water-in-diluted bitumen emulsions. Nevertheless, the demulsification mechanism of EC has not been correlated to its effect on the physical properties of stabilizing interfacial asphaltene...
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Fall 2014
Activity, selectivity and stability enhancements often observed in bimetallic catalysts make them an inseparable part of today’s chemical industry. However, it is usually problematic to understand the real interactions resulting in such improvements due to the lack of control over the bimetallic...
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Spring 2011
A Surface Forces Apparatus (SFA) was used in this study to investigate the fundamental surface forces in oil sand processing research. Asphaltene coated surfaces were chosen as the research topic due to the critical role of asphaltenes in oil sands processing, from bitumen extraction, froth...
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Fall 2016
Asphaltenes are the heaviest component in crude oil and bitumen. The molecular interactions and interfacial behaviours of asphaltenes are closely related to many challenging issues in oil production, which are believed to play an important role in stabilizing water-in-oil (W/O) and oil-in-water...
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Fall 2011
Large polycyclic aromatic nitrogen containing asphaltene model compounds, with molecular weights from 535 to 702 g/mol, were catalytically hydrogenated and hydrodenitrogenated in the presence of a commercial NiMo/γAl2O3 catalyst in a stainless steel batch reactor at 370 °C and 17.9 MPa total...
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Spring 2013
The self-association properties of two model compounds of asphaltene, 2,6-bis[2-(pyren-1-yl)ethyl]pyridine (PyPPy, C41H29N) and 2,6-bis[2-(phenanthren-9-yl)ethyl]pyridine (PhPPh, C37H29N), were studied in deuterated chloroform and deuterated methylene chloride. 1H NMR spectroscopy titration...
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Spring 2023
The development of economically viable processes for processing and transporting of heavy crude oil and bitumen are critical for continued development in the Canadian oil sands. Current technologies for preparing such crudes for transport to market include full upgrading to synthetic crude oil,...