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Spring 2013
20Cr-32Ni-1Nb stainless steel alloys are commonly used in hydrogen reformer manifolds for transporting hot hydrogen by-products at 750-950 celcius. After long periods of exposure, embrittling secondary carbides and intermetallic phases can precipitate at the grain boundaries which can drastically...
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Characterization of magnetic nanoparticles as contrast agents and their application for quantitative magnetic susceptibility monitoring of the waterflooding of heavy oil in real time
DownloadSpring 2018
Waterflooding is one enhanced oil recovery process used in heavy oil reservoirs such as at Cold Lake in North-Eastern Alberta. However, little has been published in terms of imaging heavy oil waterfloods, mainly due to the similar densities of water and heavy oil, which makes it difficult to...
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Characterization of Particulate Matter Morphology and Volatility for Two Direct-Injection Engines
DownloadFall 2015
Particulate matter emitted from two direct injection engines has been characterized by morphology, volatility, mass-mobility exponent, effective density, and size distribution using tandem measurements from a centrifugal particle mass analyzer (CPMA) and differential mobility analyzers (DMA). The...
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Chiral Transition Metal Complexes under Resonance: Mechanism of a New Form of Chiral Raman Spectroscopy
DownloadFall 2023
My PhD thesis primarily focuses on exploring chiroptical events and signatures of chiral transition metal complexes when they are under (near) resonance conditions. To achieve this goal, multiple chiroptical spectroscopic techniques were utilized, aided by theoretical calculations. These...
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Fall 2018
General Purpose computing with Graphics Processing Units (GPGPU) is a method of com-putation that allows for calculations to be performed in parallel. Graphics Processing Units(GPU) allow a single basic computer to perform as well as a super computer cluster composedof only Central Processing...
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Computational Investigation of Electrical Conductivities and Magnetism of Phosphonate Metal-Organic Frameworks and Frontier Orbital Gaps, Structure, and Proton Transfer Mechanisms in Phosphonate Hydrogen-Bonded Organic Frameworks
DownloadSpring 2024
The study of metal-organic frameworks (MOFs) and hydrogen-bonded organic frameworks (HOFs) has gained much interest over the last decade. MOFs and HOFs are constructed through the self-assembly of organic building units and metals (in the case of MOFs), giving rise to a diverse range of...
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Fall 2012
Dendritic cells (DCs) play a central role in shaping antigen-specific immune response. Antibody-mediated antigen targeting to DC-specific surface receptors is a promising approach to enhance vaccine efficacy. The objective of this thesis was to develop DC-targeted nanoparticulate formulations for...
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Dependence of the Interfacial Adhesion between Two Different Types of Material on their Electron Work Function and Electrical Conductivity
DownloadFall 2021
We observed and investigated a novel interfacial phenomenon related to the dependence of interfacial bonding or adhesive force (Fad) between two substances on the difference in their Electron Work Functions (EWF) or Δφ, and developed a model to quantify such a dependence. First, using...
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Design, Development and Mechanistic Study of Ruthenium-Based Catalysts for the Hydrogenation of Imides and Amides
DownloadSpring 2014
Prior mechanistic studies demonstrate that trans-[RuH2((R)-BINAP)((R,R)-dpen)] is a remarkably active carbonyl reducing agent at low-temperatures in THF-d8. This dissertation describes the monohydrogenation of cyclic meso-imides using this catalyst and related complexes under mild conditions....
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Development and Application of Protected Amino Acids for the Installation of Stable Post-translational Modifications Using Solid-Phase Peptide Synthesis
DownloadFall 2022
This thesis describes the synthesis of non-canonical amino acid building blocks and their use in solid-phase peptide synthesis (SPPS) to explore peptidic drug analogues based on natural products. We replaced sensitive functionalities found in the structure of naturally produced peptides with...