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Skip to Search Results- 1Ahmed, Nirob
- 1Amundarain, Jesus
- 1Ansari, Nesma Nasir
- 1Berahman, Behnam
- 1Cardozo, Samuel D.
- 1Carvalho do Prado, Glaucia H
- 6Xu, Zhenghe (Chemical and Materials Engineering)
- 3Gupta, Rajender (Chemical and Materials Engineering)
- 3Liu, Qingxia (Chemical and Materials Engineering)
- 3Zeng, Hongbo (Chemical and Materials Engineering)
- 2Gray, Murray R. (Chemical and Materials Engineering)
- 2Stryker, Jeffrey M (Chemistry)
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Scalable and Concise Approaches for the Synthesis of "Archipelago Model" Asphaltene Compounds
DownloadFall 2015
Asphaltenes constitute the most difficult sub-class of bitumen with regards to upgradability. This is due to their complex and variable structure, higher average molecular weight, and inclusion of polar functionalities. These structural traits instigate intermolecular attractions that lead to...
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Fall 2011
Liquid crystalline domains were observed in fractions of heavy petroleum. Through a combination of polarized light microscopy and Photoacoustic Infrared Spectroscopy, liquid crystals were shown to form on the exterior surface of their parent materials. Analysis of materials using Differential...
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Spring 2016
Asphaltenes are a solubility class and it is the material in oil that is insoluble in a paraffinic matrix. It is a major contributor to problems in many petroleum operations such as production, transportation, refining, precipitation, crude oil emulsification, and de-emulsification, and high...
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Spring 2010
Most crude oils contain traces of vanadyl porphyrins within their asphaltene fraction. Although these metals are only present in trace quantities, they have a significant detrimental impact on crude oil processing units; therefore, their selective removal is highly desirable. The current work...
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Studying Structure-Nanoaggregation Relations of Polyaromatic Molecules in the Bulk Oil Phase and at the Oil-Water Interface Using Molecular Dynamics Simulation
DownloadSpring 2014
The detection, identification and characterization of early stage molecular association of polyaromatic molecules into nanoaggregates, where these nanoaggregates represent the first level of molecular clusters or building blocks are critical in areas such as design and fabrication of advanced 3-D...
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The Synthesis of and Methodology for Archipelago Model Asphaltenes with a Benzo[b]anthraquinoline Core
DownloadFall 2013
The efficient synthesis of model asphaltenes as polyaromatic, nitrogenous compounds is reported. These model asphaltenes are to be used for supramolecular investigation for developing enhanced bitumen processing methodology. Our synthesis of benzo[f]quinoline and benzo[b]anthraquinoline...
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Fall 2012
Better definition of asphaltene structure is needed to develop new technology for upgrading, and to understand various bitumen properties. Analysis of asphaltene structure is hampered by aggregation of molecules at a length scale of 5 to 10 nm. At 300°C, the addition of aromatic solvents can...
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Spring 2013
Solvents are ubiquitously used in oil sands extraction industry to enhance the separation of bitumen froth. With developing new technologies such as non-aqueous bitumen extraction, the need to track solvent interactions with oil sands components throughout the extraction process and to identify...
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Fall 2017
Asphaltene is the most difficult fraction of bitumen and heavy oil to upgrade, as it has low H/C, high molecular weight and metal content. Asphaltenes are insoluble in paraffinic solvents, and undergo aggregation and coke formation during refining and cracking processes. No attention is usually...
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Spring 2017
Interactions mechanisms of deformable air bubbles and liquid droplets play critical roles in many established and modern industrial processes. Understanding the interaction mechanisms of oil droplets and air bubbles is of fundamental and practical importance to solve many challenging issues,...