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The Synthesis of and Methodology for Archipelago Model Asphaltenes with a Benzo[b]anthraquinoline Core

  • Author / Creator
    Heidt, Terry P
  • The efficient synthesis of model asphaltenes as polyaromatic, nitrogenous compounds is reported. These model asphaltenes are to be used for supramolecular investigation for developing enhanced bitumen processing methodology. Our synthesis of benzo[f]quinoline and benzo[b]anthraquinoline derivatives linked to polyaromatic hydrocarbons by alkane and alkene tethers, including structures with complex steroidal fusions, make-up an `archipelago` motif and represent current models of asphaltene structure. With an optimized acid catalyzed multicomponent reaction and an improved preparation of 1-vinylpyrene, we developed efficient syntheses of model asphaltene fragments and developed methodology for expanding our library of asphaltene compounds.

  • Subjects / Keywords
  • Graduation date
    2013-11
  • Type of Item
    Thesis
  • Degree
    Master of Science
  • DOI
    https://doi.org/10.7939/R31G0J558
  • License
    This thesis is made available by the University of Alberta Libraries with permission of the copyright owner solely for non-commercial purposes. This thesis, or any portion thereof, may not otherwise be copied or reproduced without the written consent of the copyright owner, except to the extent permitted by Canadian copyright law.
  • Language
    English
  • Institution
    University of Alberta
  • Degree level
    Master's
  • Department
    • Department of Chemistry
  • Supervisor / co-supervisor and their department(s)
    • Stryker, Jeffrey M (Chemistry)
  • Examining committee members and their departments
    • Clive, Derrick (Chemistry)
    • McCaffrey, Wiliam (Chemical and Materials Engineering)