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- 2Li, Leo
- 2Nizio, Katie D
- 1Abdel Latif Ibraheem, Ahmed Abdel Mohsen
- 1Abdelfattah, Ahmed
- 1Abel, Robin Jacob
- 1Abou-Ghanem, Maya
- 23Organic compounds. Synthesis.
- 21Capillary electrophoresis.
- 18Chemical reactions.
Synthesis, structures and reactions of hydrotris(pyrazolyl)borate complexes of divalent and trivalent lanthanidesDownload
The synthesis and reactions of hydrotris(pyrazolyl)borate, (TpR,R′) supported ytterbium(II) borohydride and lanthanide(III) dialkyl (Ln = Yb, Lu) complexes were investigated. The lanthanide(III) dialkyl complexes were found to undergo both hydrogenolysis reaction and protonolysis reaction with...
Oxonium Ylide Rearrangements: A Novel Approach Towards the Synthesis of the Phorbol SkeletonDownload
Oxonium ylides are highly reactive intermediates that can be used for the synthesis of heterocyclic and carbocyclic frameworks. These putative intermediates are almost exclusively formed from diazocarbonyl derived metallocarbenes, by attack of a pendent oxygen atom. Oxonium ylides have been...
Roxarsone® (ROX, 3-nitro-4-hydroxyphenylarsonic acid) has been used in the poultry industry to prevent coccidiosis, enhance feed efficiency, and to promote growth of the broiler chickens. However, the metabolism, distribution, and elimination of ROX from poultry are not well understood. The focus...
Self-assembly of functional groups on metal and metal oxide surfaces has been a foundation technology in micro- and nanofabrication. Confinement of reactive groups to a single molecular layer on a surface has been a rich field of scientific advancement, particularly with alkanethiolates on gold...
This thesis describes advanced model studies directed to the synthesis of CP- 225,917 and CP-263,114, complex natural products that have been shown to inhibit enzymes that are involved in cholesterol biosynthesis and in the development of many cancers. A route was devised to the functionalized...
DNA strand displacement reaction (SDR) is a fast, isothermal, and sequence specific reaction. In SDR, an invading DNA single strand, also known as the “fuel” strand, unzips a partial duplex to form a more thermodynamically stable duplex. The complementary strand to the fuel strand is referred to...
Design, Development and Mechanistic Study of Ruthenium-Based Catalysts for the Hydrogenation of Imides and AmidesDownload
Prior mechanistic studies demonstrate that trans-[RuH2((R)-BINAP)((R,R)-dpen)] is a remarkably active carbonyl reducing agent at low-temperatures in THF-d8. This dissertation describes the monohydrogenation of cyclic meso-imides using this catalyst and related complexes under mild conditions....