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Skip to Search Results- 1Chisholm, Roderick A.
- 1Du, Rongbing
- 1Harris, Kristopher J.
- 1Morteza Najarian, Amin
- 1Murray, Adrian H
- 1Reid, Michael S
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All-Carbon Molecular Electronics: From Flexible Fabrication to Multi-Step Transport and Molecular Optoelectronics
DownloadSpring 2018
The central idea of molecular electronics is to incorporate individual or ensemble molecules into the electronic circuit units in the hope of creating miniaturized functional devices with unique properties. This dissertation aims to present my efforts to pursue this ultimate goal, covering the...
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Conductive Atomic Force Microscopy Study of Electron Transport Through Diazonium Derived Films and Mixed – Mode Bonded Layers on Gold and Carbon Surfaces
DownloadSpring 2012
For Molecular Electronics to become a viable replacement or complitment to current elec- tronic devices a fundamental understanding of device operation and functionality is needed. This work explores electron transport through diazonium derived molecular junctions via conductive atomic force...
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Development of High Efficiency and New Selectivity Liquid Chromatographic Phases for the Separation of Ionic and Hydrophilic Analytes
DownloadFall 2013
Separation of low molecular weight ions and hydrophilic analytes is achieved by high performance ion chromatography (IC) and hydrophilic interaction liquid chromatography (HILIC). The goal of this thesis was three-fold: to increase the efficiency of IC separations by employing small particles; to...
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Spring 2013
Electrografting permits bonding of an organic film to a conductive substrate. It is therefore important to control the formation of organic films as best as possible and to understand the linkage between the organic film and the substrate as best as possible. This work explores electrografting of...
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Exploring Atomic Force Microscopy To Probe Charge Transport Through Molecular Films And For The Development Of Combinatorial Force Microscopy
DownloadFall 2012
Since the invention of the atomic force microscope (AFM), this technology has had profound implications in the study of material science and molecular biology. The ability to visualize and perform quantitative analysis of the nanoscale properties of surfaces has provided great insights into...
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Spring 2010
New methods to fabricate nanometer sized structures will be a major driving force in transforming nanoscience to nanotechnology. There are numerous examples of the incorporation of nanoscale structures or materials enhancing the functionality of a device. Graphitic carbon is a widely used...
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Fall 2009
This thesis is concerned with applications of modern solid-state NMR spectroscopy. Investigations of three quite different types are undertaken, each of which attempt to advance knowledge in the fields of chemistry and NMR. The goal of each project is to obtain insight into the effects of...
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Synthesis and Properties of Graphyne Model Compounds and an Electrochemical Study of Substituted Pentacenes
DownloadSpring 2013
The work described in this thesis focuses on two central topics: (1) the synthesis of carbon-rich macrocycles as model compounds of the carbon allotrope graphyne and the study of their electronic properties, and (2) the electrochemical investigation of the properties of substituted pentacene...
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Fall 2010
The electrochemical reduction of para-substituted aryldiazonium cations is a convenient method of introducing chemical functional groups to a surface. The number of conductive surfaces that have been used for this purpose is rapidly expanding. The body of work presented in this thesis will serve...
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The Influence of Specific Ions and System Architecture on the Recognition and Reactivity of Two Charged Materials: DNA-Modified Gold Nanoparticle Aggregates and Planar Silica
DownloadFall 2014
DNA functionalized gold nanoparticles (GNP–DNA) offer simple colorimetric nucleic acid sensing with high selectivity and sensitivity. Consequently, they are promising in genetic profiling, disease diagnostics, and forensic applications. In the presence of a target nucleic acid, GNP–DNA forms...