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Conductive Atomic Force Microscopy Study of Electron Transport Through Diazonium Derived Films and Mixed – Mode Bonded Layers on Gold and Carbon Surfaces

  • Author / Creator
    Reid, Michael S
  • For Molecular Electronics to become a viable replacement or complitment to current elec- tronic devices a fundamental understanding of device operation and functionality is needed. This work explores electron transport through diazonium derived molecular junctions via conductive atomic force microscopy to provide insight into the scalability of molecular de- vices. The attenuation coefficient and electron transport properties of nitroazobenzene on carbon; were found to be consistent with larger ensemble molecular junctions. Further, ap- plied force significantly decreased the resistance through the layer due to reduced tunneling distance and increased contact area. Electron transport through nitroazobenzene was ex- tended to gold surfaces and found to be in agreement with studies on carbon. Investigation of mixed-mode bonded layers of nitroazobenzene and dodecanethiol determined that surface coverage was controllable through solution concentration and sweep rate. Qualitatively it was observed that conductivity increased with nitroazobenzene coverage.

  • Subjects / Keywords
  • Graduation date
    2012-06
  • Type of Item
    Thesis
  • Degree
    Master of Science
  • DOI
    https://doi.org/10.7939/R3639KG7V
  • License
    This thesis is made available by the University of Alberta Libraries with permission of the copyright owner solely for non-commercial purposes. This thesis, or any portion thereof, may not otherwise be copied or reproduced without the written consent of the copyright owner, except to the extent permitted by Canadian copyright law.
  • Language
    English
  • Institution
    University of Alberta
  • Degree level
    Master's
  • Department
    • Department of Chemistry
  • Supervisor / co-supervisor and their department(s)
    • McDermott, Mark (Chemistry)
  • Examining committee members and their departments
    • McCreery, Richard (Chemistry)
    • Freeman, Mark (Physics)