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An Electrochemical Impedance Spectroscopic Diagnostic Device for Characterization of Liquid-Liquid Systems and Phase Separation Detection in Emulsions
DownloadFall 2013
Rapid characterization of complex fluids, especially sensing emulsion stability, is crucial for many industrial applications, ranging from pharmaceutical industry to petroleum production. Electrochemical impedance spectroscopy (EIS) is a powerful tool for electrical characterization of such...
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Spring 2016
During the extraction of crude oil or bitumen, stable water-in-oil emulsions are inevitably formed. The emulsified water contains chloride ions and other organic acidic compounds that cause severe corrosion problems to the downstream plant equipment, creating operational and safety issues and...
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Fall 2014
The formation of stable water-in-oil emulsions during bitumen extraction poses problems for water separation from diluted bitumen, which leads to equipment corrosion and catalyst fouling in downstream operations. Demulsifiers are used to break the stable emulsions and assist the separation of...
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Dynamic Demulsification Mechanism of Asphaltene-Stabilized Water-in-Oil Emulsions by Ethylcellulose
DownloadFall 2015
In previous studies, nontoxic and biodegradable ethylcellulose (EC) was shown to be capable of breaking water-in-diluted bitumen emulsions. Nevertheless, the demulsification mechanism of EC has not been correlated to its effect on the physical properties of stabilizing interfacial asphaltene...
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Fall 2012
Stabilization of water droplets in froth treatment process results in poor de-watering efficiency and potentially affects final bitumen quality. The purpose of this research is to study the effect of solid contamination by diluted bitumen on water droplet stabilization in water in oil emulsions....
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Electrocoalescence of Water Droplets in Oil Emulsions: Effect of Electric Fields, Surfactants, and Chemical Demulsifiers
DownloadSpring 2019
Stabilization of water-in-oil droplets during bitumen extraction and refining process poses a major challenge in the oil sands industry. These crude oil emulsions are stabilized by rigid films at water droplet-oil interfaces. The salty water remaining in oil causes equipment corrosion, catalyst...
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Spring 2017
The formation of stable water-in-oil emulsions during oil sands extraction process causes a number of operational issues, such as equipment corrosion, storage and transportation problems. One common method for emulsion breakup in industry is to use chemical demulsifiers. The chemical demulsifiers...
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Spring 2024
A diffuse interface model to simulate a system of two immiscible liquids with surfactants is proposed. This model is based on a modified Ginzburg-Landau free energy functional to account for non-ionic soluble surfactants and couples the Navier-Stokes equations with two Cahn-Hilliard equations...
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High-Float Emulsion Residue: A New Rheological Model Based on the Existence of a Yield Stress
DownloadFall 2016
“High-float” (HF) emulsions are dispersions of micron-sized bitumen droplets in water, with a special type of anionic surfactant functioning as stabilizer. By allowing the water to evaporate from an HF emulsion, what remains is called a “high-float emulsion residue.” Although indistinguishable in...