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Skip to Search Results- 1Chisholm, Roderick A.
- 1Du, Rongbing
- 1McGinitie, Teague M
- 1Reid, Michael S
- 1Shewchuk, Dwayne
- 1Smith, John F.
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Conductive Atomic Force Microscopy Study of Electron Transport Through Diazonium Derived Films and Mixed – Mode Bonded Layers on Gold and Carbon Surfaces
DownloadSpring 2012
For Molecular Electronics to become a viable replacement or complitment to current elec- tronic devices a fundamental understanding of device operation and functionality is needed. This work explores electron transport through diazonium derived molecular junctions via conductive atomic force...
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Development of High Efficiency and New Selectivity Liquid Chromatographic Phases for the Separation of Ionic and Hydrophilic Analytes
DownloadFall 2013
Separation of low molecular weight ions and hydrophilic analytes is achieved by high performance ion chromatography (IC) and hydrophilic interaction liquid chromatography (HILIC). The goal of this thesis was three-fold: to increase the efficiency of IC separations by employing small particles; to...
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Spring 2013
Electrografting permits bonding of an organic film to a conductive substrate. It is therefore important to control the formation of organic films as best as possible and to understand the linkage between the organic film and the substrate as best as possible. This work explores electrografting of...
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Exploring Atomic Force Microscopy To Probe Charge Transport Through Molecular Films And For The Development Of Combinatorial Force Microscopy
DownloadFall 2012
Since the invention of the atomic force microscope (AFM), this technology has had profound implications in the study of material science and molecular biology. The ability to visualize and perform quantitative analysis of the nanoscale properties of surfaces has provided great insights into...
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Spring 2010
New methods to fabricate nanometer sized structures will be a major driving force in transforming nanoscience to nanotechnology. There are numerous examples of the incorporation of nanoscale structures or materials enhancing the functionality of a device. Graphitic carbon is a widely used...
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New Approaches to Thermodynamics-based Predictive Modelling of Gas Chromatography and Comprehensive Two-dimensional Gas Chromatography
DownloadSpring 2019
Thermodynamics-based predictive models of retention in gas chromatography and comprehensive two-dimensional gas chromatography have been demonstrated to provide high prediction accuracy across a wide range of separation conditions. They generally predict better than retention index-based models...
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Fall 2010
The electrochemical reduction of para-substituted aryldiazonium cations is a convenient method of introducing chemical functional groups to a surface. The number of conductive surfaces that have been used for this purpose is rapidly expanding. The body of work presented in this thesis will serve...
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Tools and Methodologies for The Rapid Determination and Transfer of Thermodynamic Parameters used in the Prediction of Gas Chromatographic and Two Dimensional Comprehensive Gas Chromatographic Retention Times
DownloadFall 2014
Three parameter thermodynamic predictive models have been shown previously to provide superior accuracy in the prediction of gas chromatographic retention times in comparison to other forms of modelling such as retention indices. However, these models suffer from the need for extensive...