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Skip to Search Results- 1Amundarain, Jesus
- 1Ansari, Nesma Nasir
- 1Berahman, Behnam
- 1Cardozo, Samuel D.
- 1Carvalho do Prado, Glaucia H
- 1Dechaine, Greg Paul
- 6Xu, Zhenghe (Chemical and Materials Engineering)
- 3Gupta, Rajender (Chemical and Materials Engineering)
- 3Liu, Qingxia (Chemical and Materials Engineering)
- 3Zeng, Hongbo (Chemical and Materials Engineering)
- 2Gray, Murray R. (Chemical and Materials Engineering)
- 2Thundat, Thomas (Chemical and Materials Engineering)
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Spring 2016
During the extraction of crude oil or bitumen, stable water-in-oil emulsions are inevitably formed. The emulsified water contains chloride ions and other organic acidic compounds that cause severe corrosion problems to the downstream plant equipment, creating operational and safety issues and...
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Characterization of asphaltene molecular structures by cracking under hydrogenation conditions and prediction of the viscosity reduction from visbreaking of heavy oils
DownloadSpring 2013
The chemical building blocks that comprise petroleum asphaltenes were determined by cracking samples under conditions that minimized alterations to aromatic and cycloalkyl groups. Hydrogenation conditions that used tetralin as hydrogen-donor solvent, with an iron-based catalyst, allowed...
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Characterization of Athabasca asphaltenes separated physically and chemically using small-angle X-ray scattering
DownloadFall 2010
Athabasca asphaltenes were characterized using small-angle X-ray scattering (SAXS) with synchrotron radiation. Two methods were used to separate asphaltenes from Athabasca bitumen. Conventional chemical separation by precipitation with n-pentane, and physical separation realized by passing...
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Fall 2009
In this study, we describe the use of different silica materials to separate vanadium compounds from Asphaltenes. We used high performance flash chromatography separation method to separate asphaltenes at different solvent strengths on sea sand. The separation conditions were optimized for flow...
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Spring 2015
This thesis presents a thorough examination of the corrosion and fouling behaviour of crude oil at refining conditions on industrially applicable heat transfer surfaces. The depletion of light sweet crude oil reserves means that the processing of ever heavier and more sour crude oils is...
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Spring 2016
The tendency of asphaltenes to aggregate in crude oil is observed at SATP and is enhanced at elevated temperatures. At these conditions, asphaltenes aggregation is a problem as it will ultimately lead to mesophase formation, a precursor of coke, known for causing plugging and fouling of...
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Dynamic Demulsification Mechanism of Asphaltene-Stabilized Water-in-Oil Emulsions by Ethylcellulose
DownloadFall 2015
In previous studies, nontoxic and biodegradable ethylcellulose (EC) was shown to be capable of breaking water-in-diluted bitumen emulsions. Nevertheless, the demulsification mechanism of EC has not been correlated to its effect on the physical properties of stabilizing interfacial asphaltene...
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Electrocoalescence of Water Droplets in Oil Emulsions: Effect of Electric Fields, Surfactants, and Chemical Demulsifiers
DownloadSpring 2019
Stabilization of water-in-oil droplets during bitumen extraction and refining process poses a major challenge in the oil sands industry. These crude oil emulsions are stabilized by rigid films at water droplet-oil interfaces. The salty water remaining in oil causes equipment corrosion, catalyst...
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Extending Depletion Flocculation Phase Behavior Models to Partially Soluble and Aggregating Colloids—Asphaltenes
DownloadFall 2015
Mixtures of colloids + non-adsorbing polymers + good solvents are well known to exhibit multiphase behaviors that are driven by the depletion flocculation mechanism where one phase, designated a colloid gas, is largely comprised of polymer and solvent, while the other phase, designated a colloid...
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Fall 2011
The removal of solid particulates from crude oils and hydrocarbon streams is a common challenge in refining. Finding a method for efficient removal of the suspended solids in the oil streams is the main objective of this work. Paraffinic and aqueous treatment and the combination of these two...