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- 1Capillary condensation
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Comparative Surface Thermodynamic Analysis of New Fluid Phase Formation in Various Confining Geometries
DownloadSpring 2012
For a pure bulk (unconfined) fluid, phase transition happens at the saturation pressure. In contrast, for a fluid inside a confinement of small size (commonly below micrometers), vapour and liquid coexistence may happen at pressures other than the saturation pressure; or an expected phase...
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