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Development of Rhodium Catalyzed Formic Acid Mediated Z-Selective Alkene Synthesis from Electron Deficient Dienes
DownloadFall 2020
Z-Alkenes are important functional moieties in biological molecules and serve as versatile units for chemical transformations in synthetic chemistry. Synthetic strategies to readily generate these less thermodynamically stable alkenes with high regio-, chemo- and stereocontrol remain challenging,...
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Fall 2022
Cooze, Christopher Joseph Craig
The metal-catalyzed addition of nucleophiles to electron-deficient alkenes represents one of the most useful tools for the construction of carbon-carbon and carbon-heteroatom bonds. Of the methods that have been developed, the Rh-catalyzed conjugate addition of aryl and alkenyl boronic acids to...