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Cationic Rhodium JosiPhos Polymers: Pathway to Highly Reusable Catalysts for Heterogeneous Asymmetric Hydrogenation
DownloadFall 2018
JosiPhos derivatives with an alt-ROMP active norimido group. Specifically, the alt-ROMP active cationic [Rh(diphosphine)COD]BF4 (diphosphine = (R)-1-[(Sp)-2-(Diphenylphosphino)-1’-(dimethyl-3’-N-(cis-5-norbornene-2,3-dicarboximidopropylsilyl)ferrocenyl]ethyl-di-cyclohexylphosphine) compound was...
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The Synthesis of Rhodium Catalyst-Organic Frameworks for Isomerization and Continuous-Flow Hydrogenation Reactions
DownloadFall 2013
The development of immobilized asymmetric catalysts is of vital importance as it would allow for easy catalyst recovery from the reaction mixture and reuse. One strategy for immobilization involves the synthesis of insoluble polymer-supported catalysts. Most polymeric catalysts are made by...