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Modular Construction of Photoanodes with Covalently Bonded Ru- and Ir-Polypyridyl Visible Light Chromophores
Download2018-07-01
Chao Wang, Mona Amiri, Riley T. Endean, Octavio Martinez Perez, Samuel Varley, Ben Rennie, Loorthuraja Rasu, Steven H. Bergens
1,10-phenanthroline is grafted to indium tin oxide (ITO) and titanium dioxide nanoparticle (TiO2) semiconductors by electroreduction of 5-diazo-1,10-phenanthroline in 0.1 M H2SO4. The lower and upper potential limits (-0.20 and 0.15 VSCE, respectively) were set to avoid reduction and oxidation of...