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- 2Li, Leo
- 2Nizio, Katie D
- 1Abdel Latif Ibraheem, Ahmed Abdel Mohsen
- 1Abdelfattah, Ahmed
- 1Acedo, Jeella Z
- 1Achutha, Vasudevamurthy
The facile cleavage of relatively inert chemical bonds followed by their functionalization into value-added products is an important goal in chemistry. Although monometallic complexes are effective at both the cleavage of inert bonds and the subsequent functionalization of the activated...
Development and Application of ESI-MS Based Techniques to Study Non-Covalent Protein-Ligand Complexes in Solution and the Gas PhaseDownload
This thesis describes the development and application of electrospray ionization mass spectrometry (ESI-MS) based techniques to study noncovalent protein-ligand complexes in solution and the gas phase. The application of the direct ESI-MS assay for quantifying the stoichiometry and absolute...
Furanose-containing molecules are widespread in nature and have been identified as important constituents of glycoconjugates from numerous pathogenic microorganisms. Although significant advances in the synthesis of 1,2-cis-glycofuranosides have been made, there are still some challenges. In...
Studies of Fundamental Theories and Retention Mechanism of Charge Transfer and Hypercrosslinked Phases in Normal Phase High Performance Liquid ChromatographyDownload
Polar compounds in petroleum, especially compounds containing nitrogen, cause numerous problems in the processing of oil, including deactivation of catalysts, corrosion, and storage instability. Chromatographic separation helps to identify and characterize these polar compounds at different...
Development and Application of ESI-MS Based Techniques for Quantitative Determination of Protein-Carbohydrate InteractionsDownload
This thesis describes the development and application of mass spectrometry methods to study protein-ligand interactions in vitro. Liquid sample desorption electrospray ionization mass spectrometry (liquid sample DESI-MS) was employed to quantify protein-carbohydrate interactions in aqueous buffer...
The last decades witnessed the rapid growth and advancement of research on microfluidic systems for chemical and biological analysis. There remain many important biochemical challenges that need to be solved with novel technologies. This thesis looks at how to apply several microfluidic...
Cationic Rhodium JosiPhos Polymers: Pathway to Highly Reusable Catalysts for Heterogeneous Asymmetric HydrogenationDownload
JosiPhos derivatives with an alt-ROMP active norimido group. Specifically, the alt-ROMP active cationic [Rh(diphosphine)COD]BF4 (diphosphine = (R)-1-[(Sp)-2-(Diphenylphosphino)-1’-(dimethyl-3’-N-(cis-5-norbornene-2,3-dicarboximidopropylsilyl)ferrocenyl]ethyl-di-cyclohexylphosphine) compound was...