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Spring 2015
This thesis is focused on the silicon-based anode materials for lithium-ion batteries (LIBs) as well as germanium-based electrode materials for sodium-ion batteries (NIBs). In our first attempt we studied electrochemical cycling stability and degradation mechanisms of silicon nanowires (SiNWs)...
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Spring 2017
We present the characterization of close-spaced linear dangling bond structures, or dangling bond chains, two to seven dangling bonds long, on a hydrogen terminated silicon (100)-2x1 surface using a scan- ning tunnelling microscope. Constant height differential conductance maps reveal their local...
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Fall 2015
Dangling Bonds (DBs) on the silicon surface exist when a silicon atom lacks a bonding partner, resulting in a localized orbital which is not involved in any chemical bonds. On the hydrogen-terminated Si(100) surface, such DBs introduce a mid-gap state. DBs can be created on this surface by the...
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Spring 2011
The field of plasmonics has offered the promise to combine electronics and photonics at the nanometer scale for ultrafast information processing speeds and compact integration of devices. Various plasmonic waveguide schemes were proposed with the potential to achieve switching functionalities and...
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Silicon Nanoparticles from the Inside Out: Exploring the Internal Structure of Silicon Nanoparticles and Its Impact on Their Photoluminescence
DownloadFall 2020
Silicon nanoparticles (SiNPs) have garnered significant attention as a biologically compatible alternative to traditional quantum dots. SiNPs are well suited for a wide range of applications due to their photoluminescence (PL) and chemical properties. These advantageous properties can be...
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Fall 2014
The objective of this research was to explore the feasibility of using SPI nanoparticles to improve the absorption of vitamin B12 (VB12) using in-vitro and ex-vivo models. The molecular interactions between soy proteins and VB12 were firstly studied and the results revealed that VB12 was bound to...
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Synthesis and Application of Colloidal Substrates for In-Solution Surface Enhanced Raman Scattering
DownloadFall 2020
Surface-enhanced Raman scattering (SERS) has evolved into a powerful analytical measurement technique with the potential for single molecule detection. The technological advancement of handheld Raman instrumentation is powering the development of SERS applications in a variety of industries....
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Spring 2012
Germanium nanomaterials have many potential applications based on their size-tunable optical and electronic properties, for example in photodetectors, photovoltaics and non-volatile memory. In this work, the synthesis of Ge nanoparticles by two different methods based on tailorability through the...
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Fall 2020
The synthesis of germanium nanomaterials with well-defined surface chemistry is of considerable interest, not only because of general scientific curiosity but also because of their vast potential applications in optoelectronics, energy storage, and the semiconductor industry. Covalently bonded...
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Synthesis and screening of heterogeneous multimetallic nanoparticle catalysts for mono-, poly- and heteroaromatic hydrogenation activity under mild conditions
DownloadFall 2011
Nanoparticle catalysts have shown to be advantageous over traditional catalysts for many reasons and active for a wide variety of reactions. This thesis describes an approach for the synthesis and screening of heterogeneous multimetallic nanoparticle catalysts for aromatic hydrogenation activity...