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Scalable and Concise Approaches for the Synthesis of "Archipelago Model" Asphaltene Compounds
DownloadFall 2015
Asphaltenes constitute the most difficult sub-class of bitumen with regards to upgradability. This is due to their complex and variable structure, higher average molecular weight, and inclusion of polar functionalities. These structural traits instigate intermolecular attractions that lead to...
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Fall 2015
The synthesis of functionalized quinolines is described herein. Utilizing condensation reactions, derivatized quinolines were prepared to serve as nitrogen-containing asphaltene islands. Basic halogenated phenylquinolines were synthesized via urea condensations. Highly substituted quinolines...
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The Synthesis of and Methodology for Archipelago Model Asphaltenes with a Benzo[b]anthraquinoline Core
DownloadFall 2013
The efficient synthesis of model asphaltenes as polyaromatic, nitrogenous compounds is reported. These model asphaltenes are to be used for supramolecular investigation for developing enhanced bitumen processing methodology. Our synthesis of benzo[f]quinoline and benzo[b]anthraquinoline...