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Skip to Search Results- 2Shen, Jing
- 1Beckers, Nicole
- 1Brown, Houston J. S.
- 1Brown, Orain, A
- 1Bunquin, Jeffrey
- 1Cho, Byong Kwon.
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A New Approach to Molecular Hydrodesulfurization Catalysts: Allyl-capped Trialkylphosphoranimide-bridged Late First-row Transition Metal Clusters
DownloadFall 2017
A series of new trialkylphosphoranimide allyl-capped clusters [M(ƞ3-allyl)(NPR)3]2, (M = Fe, Co or Ni, R = Et, tBu or Ph) were synthesized. The nickel dimers [Ni(ƞ3-allyl)(NPR3)]2, R = Et, Ph are diamagnetic and have been fully characterized using NMR spectroscopy, X-ray crystallography,...
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Archipelago Model Compound Synthesis by Rhodium-catalyzed Annulations of Island-tethered Alkynes with Aromatic Substrates
DownloadFall 2022
Asphaltenes are the most complex constituents in bitumen. They are distinguished from other components in bitumen by high density, high viscosity and a strong tendency to form aggregates in solutions. Asphaltene aggregates may precipitate as a result of small environmental changes, which is...
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Spring 2021
A thorough overview of esters and their reductions is presented. A large focus was placed on reductions via homogeneous catalytic hydrogenation. Although several ester hydrogenation systems have been developed, the production of highly enantioenriched alcohols has generally relied upon the usage...
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Spring 2011
Selective ring opening of naphthenic molecules is a preferred reaction to increase cetane number of fuels, and it should result in products with no loss in molecular weight and longer alkyl side chains. Benzocyclopentane (indan) ring opening was studied under hydrogen atmospheric pressure at 609...
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Fall 2014
Activity, selectivity and stability enhancements often observed in bimetallic catalysts make them an inseparable part of today’s chemical industry. However, it is usually problematic to understand the real interactions resulting in such improvements due to the lack of control over the bimetallic...
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Breaking New Ground with the Suzuki-Miyaura Reaction: Stereoselective Cross-Couplings of 1,1-Diboronyl Alkanes
DownloadFall 2015
Synthetic organic chemistry is an area that has seen incredible growth through the years. The level of molecular complexity that can be achieved through available synthetic methods today is remarkable. Still, as the field continues to progress, increasing focus is being placed upon the strategic...
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Spring 2013
In every thermal upgrading process, short-chain hydrocarbons contain a part of the gas byproducts. These compounds are hydrogen-rich materials, which are considered as low value wastes. In this study, the efforts were made to catalytically convert these off-gases to liquid fuels. Synthetic gases...
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Cationic Rhodium JosiPhos Polymers: Pathway to Highly Reusable Catalysts for Heterogeneous Asymmetric Hydrogenation
DownloadFall 2018
JosiPhos derivatives with an alt-ROMP active norimido group. Specifically, the alt-ROMP active cationic [Rh(diphosphine)COD]BF4 (diphosphine = (R)-1-[(Sp)-2-(Diphenylphosphino)-1’-(dimethyl-3’-N-(cis-5-norbornene-2,3-dicarboximidopropylsilyl)ferrocenyl]ethyl-di-cyclohexylphosphine) compound was...
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Cost-Effective Catalysts for the Electrochemical and Photoelectrochemical Reduction of Carbon Dioxide
DownloadFall 2019
The growing consumption of fossil resources has rapidly depleted fuel availability and increased CO2 emission, which presents two of the most prominent crises in the modern era. CO2 reduction reaction (CO2RR) at ambient conditions using electrochemical (EC) and photoelectrochemical (PEC) methods...