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Metal particle catalyst formation from thin films for the creation of vertically aligned carbon nanotube structures

  • Author / Creator
    Olsen, Brian
  • This work contains research associated with the metal catalysts used in the formation of vertically aligned carbon nanotube (VACNT) films through catalytic chemical vapour deposition (CCVD). The solid-state dewetting process of thin metal films is studied using Ni. In the dewetting process, grain growth is followed by hole nucleation and growth at grain boundaries due to thermal grooving and curvature induced surface diffusion respectively. Coarsening continues after the percolation limit due to Ostwald and Smoluchowski ripening. A 2 nm Cr50Fe35Ni15 catalyst is found to grow the tallest VACNT films. This catalyst is found to have excellent stability against coarsening. This stability is found to be the result of Cr oxide that forms before the sample enters the CCVD reactor, but does not reduce in the reactor environment. The VACNT film is comprised of multi-walled carbon nanotubes (MWCNT) produced through base growth and whose average diameter is ∼12 nm.

  • Subjects / Keywords
  • Graduation date
    2011-11
  • Type of Item
    Thesis
  • Degree
    Master of Science
  • DOI
    https://doi.org/10.7939/R31607
  • License
    This thesis is made available by the University of Alberta Libraries with permission of the copyright owner solely for non-commercial purposes. This thesis, or any portion thereof, may not otherwise be copied or reproduced without the written consent of the copyright owner, except to the extent permitted by Canadian copyright law.
  • Language
    English
  • Institution
    University of Alberta
  • Degree level
    Master's
  • Department
    • Department of Chemical and Materials Engineering
  • Supervisor / co-supervisor and their department(s)
    • David Mitlin (Chemical and Materials Engineering)
  • Examining committee members and their departments
    • Karthik Shankar (Electrical and Computer Engineering)
    • Weixing Chen (Chemical and Materials Engineering)