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Formation of Enol Ethers by Radical Decarboxylation of α-Alkoxy β-Phenylthio Acids.
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- Author(s) / Creator(s)
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Enol ethers are formed by radical decarboxylation of -alkoxy -phenylthio acids via the
corresponding Barton esters. The phenylthio acids were usually made by the known
regioselective reaction of ,-epoxy acids with PhSH in the presence of InCl3, followed by Oalkylation
of the resulting alcohol. In one case thiol addition to an ,-unsaturated ethoxymethyl
ester was used. -
- Date created
- 2019-01-01
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- Type of Item
- Article (Draft / Submitted)
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- License
- This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Organic Chemistry, copyright © 2019 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.9b02042.