Formation of Enol Ethers by Radical Decarboxylation of α-Alkoxy β-Phenylthio Acids.

• Author(s) / Creator(s)

  • Palanivel, Ashokkumar
  • Mubeen, Sidra
  • Warner, Thomas
  • Ahmed, Nayeem
  • Clive, Derrick L. J.

• Enol ethers are formed by radical decarboxylation of -alkoxy -phenylthio acids via the
  corresponding Barton esters. The phenylthio acids were usually made by the known
  regioselective reaction of ,-epoxy acids with PhSH in the presence of InCl3, followed by Oalkylation
  of the resulting alcohol. In one case thiol addition to an ,-unsaturated ethoxymethyl
  ester was used.

• Date created

  2019-01-01

• Subjects / Keywords

  • Carboxylic-acids
  • Conjugate Addition
  • Vynyl Ethers
  • Olefin Isomerization
  • Anodic-Oxidation
  • Chain Reactions
  • Esters
  • Derivatives
  • Metathesis
  • Invention

• Type of Item

  Article (Draft / Submitted)

• DOI

  https://doi.org/10.7939/r3-tdc6-1376

• License

  This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Organic Chemistry, copyright © 2019 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.9b02042.