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Formation of Enol Ethers by Radical Decarboxylation of α-Alkoxy β-Phenylthio Acids
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- Author(s) / Creator(s)
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Enol ethers are formed by radical decarboxylation of α-alkoxy β-phenylthio acids via the corresponding Barton esters. The phenylthio acids were usually made by the known regioselective reaction of α,β-epoxy acids with PhSH in the presence of InCl3, followed by O-alkylation of the resulting alcohol. In one case, thiol addition to an α,β-unsaturated ethoxymethyl ester was used.
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- Date created
- 2019-08-29
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- Subjects / Keywords
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- Type of Item
- Article (Draft / Submitted)
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- License
- © American Chemical Society, 2019. This is an open access article which is free to download and share.