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Permanent link (DOI): https://doi.org/10.7939/R33664

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Characterization of residue from direct coal liquefaction and determination of its potential applicability as a source of fuel Open Access

Descriptions

Other title
Subject/Keyword
coal liquefaction residue
residue characterization
residue gasification
Type of item
Thesis
Degree grantor
University of Alberta
Author or creator
Iyer, Nitya A
Supervisor and department
Gupta, Rajender (Chemical and Materials Engineering)
De Klerk, Arno (Chemical and Materials Engineering)
Examining committee member and department
Chung, Hyun-Joong (Chemical and Materials Engineering)
Department
Department of Chemical and Materials Engineering
Specialization
Chemical Engineering
Date accepted
2015-01-28T14:48:36Z
Graduation date
2015-06
Degree
Master of Science
Degree level
Master's
Abstract
Direct coal liquefaction is a technology for producing liquid products from coal. One of the by-products from this process is coal liquefaction residue, which is remaining coal that was not converted to liquid products during the liquefaction process. The residue is enriched in mineral matter and the organic content is more refractory.The objective of our work was to characterize the residue produced under different DCL operating conditions and to evaluate the performance of the residue as a feed for gasifcation and combustion. The feed to the direct coal liquefaction process was Canadian sub-bituminous Coal Valley (CV) coal. The industrial solvents employed were hydrotreated (under N2 and H2) and non-hydrotreated poly-aromatic hydrocarbons (under N2). Different residues were obtained from the process, conducted at four different temperatures ranging from 300-450 C in an autoclave reactor (0.25 L) at an initial pressure of 20 bar. Coal liquid yields obtained for liquefaction using hydrotreated solvent were found to be much better, under the same operating conditions. Thus, effect of solvent and temperature in coal liquefaction is discussed briefly. The residues were further characterized for their mineral composition, organic content and particle sizes using various standard techniques: Thermogravimetic analyser (TGA), elemental analyser, mastersizer, FTIR spectrometer, X-ray fluorescence, surface area analyser. A great deal of variation in the chemical and physical composition of the residues were observed and found to be closely related to the efficiency of the process. In order to further investigate the potential applicability of liquefaction residues as a feedstock for boilers and gasifiers, the residues from the Coal Valley sub-bituminous coal liquefaction in hydrotreated solvent (N2) were gasified in a TGA. This proved to be a useful platform for comparison of the reactivity of the residues with that of raw coal. The kinetic parameters for the process were also determined under isothermal gasification conditions at temperatures 800 C, 950 C and 1000 C under O2 and at 950 C, 1000 C and 1100 C under CO2. Further, in order to determine the practical applicability of the coal residues as boiler feed, an entrained flow reactor (drop tube furnace) was employed to test the conversion efficiency of the residues. Though higher carbon conversion were found for residues, compared to raw coal, similar concerns due to ash-slagging would be prevalent for both cases.
Language
English
DOI
doi:10.7939/R33664
Rights
Permission is hereby granted to the University of Alberta Libraries to reproduce single copies of this thesis and to lend or sell such copies for private, scholarly or scientific research purposes only. Where the thesis is converted to, or otherwise made available in digital form, the University of Alberta will advise potential users of the thesis of these terms. The author reserves all other publication and other rights in association with the copyright in the thesis and, except as herein before provided, neither the thesis nor any substantial portion thereof may be printed or otherwise reproduced in any material form whatsoever without the author's prior written permission.
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