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- 1Benzene
- 1Conjugate addition elimination
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Studies towards total synthesis of MPC1001F - a triketopiperazine- dihydrooxepin natural product
DownloadSpring 2013
The thesis describes synthetic studies towards MPC1001F, a triketopiperazine-dihydrooxepin natural product. Another related member of this class of natural products is MPC1001 with an epidithiodioxopiperazine core and potent antitumor activity. Our goal was to construct the molecular skeleton of...
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Spring 2010
The first chapter of this thesis represents the continued development of a general method for the formation of benzo-fused N-heterocycles by formal radical cyclization onto benzene rings. Important stages in this process involve 1) the copper-mediated coupling of various amino alcohols to...