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- 33Mass-spectrometry
- 24Chemistry
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Fall 2018
Transition-metal catalyzed cross-coupling reactions are a broad set of tools that enable the generation of molecular complexity by coupling together molecular pieces. This is done by the use of activating groups on the molecular pieces and a metal-based catalyst. These methods are widely used in...
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Oxonium Ylide Rearrangements: A Novel Approach Towards the Synthesis of the Phorbol Skeleton
DownloadSpring 2010
Oxonium ylides are highly reactive intermediates that can be used for the synthesis of heterocyclic and carbocyclic frameworks. These putative intermediates are almost exclusively formed from diazocarbonyl derived metallocarbenes, by attack of a pendent oxygen atom. Oxonium ylides have been...
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