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A General Route to meta-(Arylsulfanyl) and meta-(Alkylsulfanyl) Substituted Phenols and Synthetic Studies on Sorbicillactones A and B
DownloadSpring 2022
Chapter 1 describes a general route for making meta-(arylsulfanyl) and meta-(alkylsulfanyl) phenols using DBU assisted aromatization developed in this laboratory. Thismethod is general and enables the construction of the C-S bond without using high temperatures or transition metal catalyst. The...
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Conversion of Cycloalk-2-en-1-ones into 2-Methylcycloalkane-1,3-diones and Formation of meta-Substituted Phenols
DownloadSpring 2016
The first chapter of this thesis describes the studies towards conversion of cycloalk-2-enones into 2-methylcyclo-alkane-1,3-diones. The key step is a Tamao–Fleming oxidation where a silyl group serves as a masked hydroxy group. Examination of various Tamao-Fleming procedures are discussed. In...