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- 24Chemistry
- 23Organic compounds. Synthesis.
- 22Metabolomics
- 21Capillary electrophoresis.
- 21Catalysis
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Empowering the Base Metals: Rational Design of Homogeneous Catalysts for Hydrotreatment, and Reduction of Organic Unsaturates
DownloadFall 2013
Hydrocarbon-soluble, low-coordinate, phosphoranimide-supported complexes of the base metals (iron, cobalt and nickel) were developed and evaluated for a range of stoichiometric and catalytic bond-forming and bond-breaking transformations. An unprecedented family of tetrametallic clusters of Co(I)...
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Enantioenriched Cyclic Boronates as Versatile Building Blocks: Synthesis, Mechanism and Applications
DownloadSpring 2020
Since the discovery and development of the famed Suzuki-Miyaura cross-coupling reaction, organoboron compounds have gained increasing attention as small molecule building blocks in organic synthesis and drug discovery efforts. In this regard, enantioenriched alkyl boronic esters are ideal...
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Spring 2011
This thesis discusses the fate of individual enantiomers and isomers of organohalogen compounds (OHCs) in the environment and the development of analytical methods to facilitate such determinations. A novel proof of principle anion attachment atmospheric pressure photoionization (AA-APPI)...
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Fall 2011
Propargylic alcohol natural products are found in many species of terrestrial plants and marine organisms. Because these compounds are usually isolated from the natural source in only small amounts, few studies of propargylic alcohol natural products have been conducted to date. Nevertheless,...
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Enantioselective Preparation of a cis-β-Boronyl Cyclobutylcarboxyester Scaffold and Its Highly Diastereoselective Nickel/Photoredox Dual-Catalyzed Cross-Coupling
DownloadSpring 2021
Chiral cyclobutanes are components of numerous bioactive natural products and consequently they have also gained significant attention in medicinal chemistry. Optically enriched cyclobutylboronates can serve as valuable synthetic intermediates for the synthesis of a broad variety of chiral...
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Energy Storage Materials: Mitigating the Degradation of Alloy-based Anodes for Lithium and Sodium Ion Batteries
DownloadSpring 2023
Lithium ion batteries have become a ubiquitous technology for consumer electronics and electric vehicles. Alloying anodes, such as silicon and tin, offer large increases in volumetric energy density compared to conventional graphite anodes. However, the alloying mechanism is accompanied by an...