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Spring 2019
The presence of complex polycyclic skeletons is a commonly encountered phenomenon in natural products and biologically active compounds. Having diverse synthetic approaches for accessing them is vital for the effective development of the pharmaceutical industry. Among other strategies, pericyclic...
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Triplet-Triplet Energy Transfer in Organic Synthesis: Efforts toward a Chiral Lewis Acid Catalyzed De Mayo Reaction and Investigations of a Photoactive Ruthenium(polypyridyl)-NHC Complex
DownloadFall 2021
The fundamentals of energy transfer catalysis and its application in [2+2] photocycloadditions are thoroughly discussed. The De Mayo reaction is a UV light-promoted [2+2] photocycloaddition between enolic β-diketones and olefins that has been used to form α-substituted 1,5-diketones. Its...