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Fall 2015
2015 marks the 50th anniversary of Moore's law, which has described the exponential progress in semiconductor patterning technologies, enabling creation of smaller circuitry features at greater densities. These continued hardware developments, economically mass manufactured, have made possible...
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Fall 2019
A novel nopoldiol-benzoxaborolate cross-link formed by a bioorthogonal click reaction between nopoldiol- and benzoxaborole-based components was developed for the preparation of biomaterials such as hydrogels and nanogels. In contrast to the traditional boronic ester-based cross-links, this...
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Fall 2022
The work in this Thesis describes significant progress made in the field of frustrated Lewis pairs (FLPs) at the intersection between modern main group chemistry and materials chemistry. Mainly, this work focuses on the use of an intramolecular phosphine-borane FLP (namely, o-iPr2P(C6H4)BCy2 or...
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Tuning π-Conjugated Polymers with Heteroatoms: Synthesis of Polytellurophenes and Soluble Polyacetylenes
DownloadFall 2021
This Thesis describes the synthesis and investigation of π-conjugated oligomers and polymers with optoelectronic properties affected by the presence of a heteroatom. Two major classes of polymers are discussed: 1) polytellurophenes, where the backbone is formed by 5-membered heterocycles...