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Application of Metallocarbene Decomposed from Diazoesters with Organic Azides and 1,2,3-Triazoles
DownloadSpring 2016
Metallocarbenes, in situ generated from catalytic decomposition of diazocarbonyl compounds, contain only 6 electrons at carbon center, therefore are highly electrophilic. Over the years, the metallocarbene intermediates have been continuously explored as a versatile tool toward C-C and C-X bond...
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Domino Azide-Metallocarbene Coupling and Nucleophilic Trapping: Synthetic Applications and Mechanistic Studies.
DownloadSpring 2016
Metallocarbenes are a class of reactive intermediates used in many strategic and complementary carbon-carbon and carbon-heteroatom bond forming reactions. The Stevens [1,2]-rearrangement of ammonium ylides is an example of a transformation typically involving metallocarbenes. The replacement of...