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Fall 2022
Peptides can elicit a whole host of beneficial physiological effects. The market for peptide-based therapeutics is rapidly expanding due to their extreme specificity and low toxicity. Conversely, they often possess poor bioavailability, stability, pharmacokinetics and cell permeability, limiting...
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Fall 2009
In an attempt to expand the scope of titanacyclobutenes, malonate-derived α,ω-alkylpropargyl dibromides and α,ω-bis(bromopropargyl) malonates were prepared and examined for their reactivity with titanocene reagents. Unfortunately, all of the α,ω-alkylpropargyl dibromomalonates failed, presumably...