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Isolation of Reactive Main Group Species by Anionic N-Heterocyclic Olefin and Terphenyl Ligands
DownloadFall 2024
The work in this Thesis describes the preparation of a new vinylithium reagent, [(MeIPrCH)Li]2 (MeIPr = (MeCNDipp)2C:; Dipp = 2,6-iPr2C6H3), which was utilized as a general source for the anionic N-heterocyclic olefin (aNHO) [(MeIPrCH)]–, a potential 2σ, 2π-electron donor. Utilizing...
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Promoting Influence of Doping Indium into BaCe0.5Zr0.3Y0.2O3- δ on the Chemical Stability, Sinterability and Electrical Properties
DownloadFall 2014
The application of BaCe1-x-yZrxYyO3-δ series solid proton conductors in SOFCs is restricted by the trade-off among the chemical stability, sinterability and electrical conductivity under SOFCs operating conditions. The present research attempted to enhance the chemical stability, sinterability...