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Fall 2024
Transition metal carbide catalysts (TMCs), particularly Molybdenum carbide (Mo2C), have emerged as a cost-effective and promising alternative to precious-metal-based catalysts (Pt, Ru) for the hydrodeoxygenation (HDO) of biomass-derived species, including bio-oil. However, low selectivity towards...
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Spring 2018
A series of phosphoranimide-supported first-row transition metal clusters were prepared, structurally characterized, and investigated for catalytic hydrogenolysis of carbon-heteroatom bonds. Homoleptic heterocubane clusters, as well as two-dimensional bi- and tetranuclear compounds of manganese,...
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Mixed-Valence First-Row Metal Clusters for Catalytic Hydrodesulfurization and Hydrodeoxygenation
DownloadFall 2013
Salt metathesis between CoCl2 and [KNPEt3]n provides a new route to the halide-substituted cobalt phosphoranimide cluster [CoCl(NPEt3)]4. This cluster is a useful precursor for the preparation of alkyl-capped cobalt phosphoranimide complexes. The methylated heterocubane [CoMe(NPEt3)]4 was...
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Production of renewable diesel through the hydroprocessing of lignocellulosic biomass derived bio oil: A review
Download2016-01-01
Due to the scarcity of fossil fuels and to population increases, there is an urgent need for renewable energy sources that can replace petroleum-derived fuels. Lignocellulosic biomass, a renewable resource, can be converted to bio-oil by fast pyrolysis and further upgraded to renewable diesel...