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Mechanistic Investigation, Development and Synthetic Applications of a Catalytic Enantioselective and Diastereoselective Allylboration Methodology
DownloadFall 2009
Over the past two decades and continuing on, carbonyl allylation chemistry has been a very useful and popular tool for the stereocontrolled formation of carbon-carbon bonds in the field of organic synthesis. In the context of natural product synthesis, the efficiency and status of aldehyde...
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Optimization and Applications of the Catalytic Enantioselective Borylative Migration of Functionalized Piperidines
DownloadFall 2016
The catalytic enantioselective borylative migration developed in 2009 by our laboratory is a convenient, single-step method that provides enantiomerically enriched heterocyclic allylboronates. However, this chemistry occasionally provided lower yields and enantioselectivity when used with...