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A New Approach to Molecular Hydrodesulfurization Catalysts: Allyl-capped Trialkylphosphoranimide-bridged Late First-row Transition Metal ClustersDownload
A series of new trialkylphosphoranimide allyl-capped clusters [M(ƞ3-allyl)(NPR)3]2, (M = Fe, Co or Ni, R = Et, tBu or Ph) were synthesized. The nickel dimers [Ni(ƞ3-allyl)(NPR3)]2, R = Et, Ph are diamagnetic and have been fully characterized using NMR spectroscopy, X-ray crystallography,...
Development of Ir- and Rh-Catalyzed Deoxygenation and Carbene Cross Coupling Reactions of Allylic CarbonatesDownload
Transition metal-catalyzed allylic substitution reactions are widely used for the selective formation of new bonds. This class of reaction has been extensively studied with a variety of nucleophiles and under optimized conditions that will furnish product in high yield and with high chemo-,...