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- 24Chemistry
- 23Organic compounds. Synthesis.
- 22Metabolomics
- 21Capillary electrophoresis.
- 21Catalysis
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Investigation of Strain-Activated Trapping Reactions of 1,2-Cyclohexadiene: Intramolecular Capture by Pendent Furans and Styrenes
DownloadFall 2020
1,2-Cyclohexadiene is a small carbocyclic allene that as a reactive intermediate can be utilized in a variety of reaction pathways. The chemical literature around this species is largely limited to various methods of generation and simple trapping reactions. Little research exists on methods to...
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Investigation of the biosynthesis of lovastatin and cytochalasin E, two fungal polyketides assembled by iterative PKS-NRPS enzymes
DownloadFall 2015
Cytochalasin E and lovastatin are two fungal polyketides that have seen extensive use as an angiogenesis inhibitor and as a cholesterol-lowering agent, respectively. These structurally divergent compounds are synthesized by polymerization of acetate units with concomitant functionalization by two...
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Investigation of the Synthesis, Reactivity and Biological Properties of Various 6-Substituted D-Fructose Derivatives
DownloadFall 2017
The detection of small tumors growing in complex organs, including breast tissue, is a challenge in modern medical imaging. The use of positron emission tomography (PET) and tracer molecules containing radionuclei such as 18F have been of significant value to detect small tumors. The commonly...