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Formal radical cyclization onto aromatic rings, cascade intramolecular conjugate displacement and synthetic studies on marinopyrroles
DownloadFall 2011
The first chapter of this thesis describes the development of a general method for indirectly effecting radical carbocyclization of an alkyl chain onto an aromatic ring. This process involves a Birch reductive alkylation of aromatic tert-butyl esters, chromium(VI)-mediated oxidation and radical...
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