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Enantioselective Preparation of a cis-β-Boronyl Cyclobutylcarboxyester Scaffold and Its Highly Diastereoselective Nickel/Photoredox Dual-Catalyzed Cross-Coupling
DownloadSpring 2021
Chiral cyclobutanes are components of numerous bioactive natural products and consequently they have also gained significant attention in medicinal chemistry. Optically enriched cyclobutylboronates can serve as valuable synthetic intermediates for the synthesis of a broad variety of chiral...
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Fall 2018
Transition-metal catalyzed cross-coupling reactions are a broad set of tools that enable the generation of molecular complexity by coupling together molecular pieces. This is done by the use of activating groups on the molecular pieces and a metal-based catalyst. These methods are widely used in...