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- 1Huang, Jin Tony.
- 1McDonald, Robert.
- 1Muritu, John Waititu.
- 1Oke, Okemona Efe
- 1Thomas, Bryce N
- 1Xiao, Jianliang.
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Development of Ir- and Rh-Catalyzed Deoxygenation and Carbene Cross Coupling Reactions of Allylic Carbonates
DownloadFall 2016
Transition metal-catalyzed allylic substitution reactions are widely used for the selective formation of new bonds. This class of reaction has been extensively studied with a variety of nucleophiles and under optimized conditions that will furnish product in high yield and with high chemo-,...
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First-Row Transition Metal-Mediated Reactions: Catalytic Ester Hydrogenolysis, Aerobic Alkane Oxidation, and [5+2] Ring-Expansion Reactions
DownloadSpring 2014
The research described in this dissertation focuses on first-row transition metal catalyzed and mediated organic reactions. The first part of the thesis involves the exploration of the catalytic reactivity of phosphoranimide-supported tetrametallic nickel and cobalt clusters, while the second...
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