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Fall 2009
The use of transition metal catalysts - either homogeneous (discrete well-defined metal complexes) or heterogeneous (more poorly-defined metal surfaces) - play an important role in the transformations of small substrates into larger, value-added compounds. Although heterogeneous catalysts have...
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Synthesis and Application of Colloidal Substrates for In-Solution Surface Enhanced Raman Scattering
DownloadFall 2020
Surface-enhanced Raman scattering (SERS) has evolved into a powerful analytical measurement technique with the potential for single molecule detection. The technological advancement of handheld Raman instrumentation is powering the development of SERS applications in a variety of industries....
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Spring 2012
Germanium nanomaterials have many potential applications based on their size-tunable optical and electronic properties, for example in photodetectors, photovoltaics and non-volatile memory. In this work, the synthesis of Ge nanoparticles by two different methods based on tailorability through the...
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Fall 2020
The synthesis of germanium nanomaterials with well-defined surface chemistry is of considerable interest, not only because of general scientific curiosity but also because of their vast potential applications in optoelectronics, energy storage, and the semiconductor industry. Covalently bonded...
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Synthesis and screening of heterogeneous multimetallic nanoparticle catalysts for mono-, poly- and heteroaromatic hydrogenation activity under mild conditions
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Nanoparticle catalysts have shown to be advantageous over traditional catalysts for many reasons and active for a wide variety of reactions. This thesis describes an approach for the synthesis and screening of heterogeneous multimetallic nanoparticle catalysts for aromatic hydrogenation activity...
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Spring 2022
Nanomaterials based upon Group 14 elements (i.e., silicon and germanium) are drawing a great deal of attention from researchers since they are biocompatible and exhibit unique optical and electronic properties. Surface functionalization, which is one of the most critical aspects of nanomaterial...
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Synthesis of fragments of a polysaccharide from Nocardia nova for structural and biological studies
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Nocardia are gram-positive bacteria. Nocardia nova is one of the Nocardia species and can cause serious disease, particularly in immunocompromised patients. Rapid diagnosis of N. nova can be lifesaving. The cell wall of N. nova contains an unusual glucose-modified arabinogalactan polysaccharide...
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Fall 2017
The elements of Group 14 show an extensive range of chemical behaviors. Lying at the boundary between metals and non-metals, some members of Group 14, namely silicon and germanium, are intermediate in their properties. These semiconductors are extremely important in science and technology. Si,...
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Synthesis, Surface Functionalization of Germanium Nanoparticles, and Their Application in Polymer Hybrid Solar Cells
DownloadSpring 2020
Germanium nanoparticles (GeNPs) have immense potential in various applications, such as opto-electronics, batteries, bioimaging, etc. Germanium has a small band gap (0.67 eV in bulk), large exciton Bohr radius (~24 nm), high absorption coefficient (ca. 2.0 × 105 cm 1 at 2 eV), and high carrier...
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Synthetic Main Group and Transition Metal Targets for Electronic and Photovoltaic Applications
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The work presented herein is focused on the synthesis and characterization of inorganic materials for potential use in electronic and photovoltaic applications. Platinum containing complexes of the form LxPt(SC4H2Br)2 (x = 1, L = dppe, dppp; x = 2, L = PBu3, PAr3), were synthesized using...