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Skip to Search Results- 7Hydrodesulfurization
- 6Palladium
- 3Bimetallic catalysts
- 3Catalysis
- 3Phosphorane imide
- 2Hydrodeoxygenation
- 2Shen, Jing
- 1Abdurrahim, Amna E.
- 1Brown, Houston J. S.
- 1Brown, Orain, A
- 1Bunquin, Jeffrey
- 1Clive, Derrick L. J.
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Spring 2018
A series of phosphoranimide-supported first-row transition metal clusters were prepared, structurally characterized, and investigated for catalytic hydrogenolysis of carbon-heteroatom bonds. Homoleptic heterocubane clusters, as well as two-dimensional bi- and tetranuclear compounds of manganese,...
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Mixed-Valence First-Row Metal Clusters for Catalytic Hydrodesulfurization and Hydrodeoxygenation
DownloadFall 2013
Salt metathesis between CoCl2 and [KNPEt3]n provides a new route to the halide-substituted cobalt phosphoranimide cluster [CoCl(NPEt3)]4. This cluster is a useful precursor for the preparation of alkyl-capped cobalt phosphoranimide complexes. The methylated heterocubane [CoMe(NPEt3)]4 was...
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Spring 2017
Fortuitous characterization of the cationic nickel cluster [Ni4(NPtBu3)4][Li3Br4(Et2O)3] led to the rational syntheses and characterization of the mixed-valence low-coordinate cationic nickel cluster: [Ni4(NPtBu3)4]BPh4 and [Ni4(NPtBu3)4]PF6, and subsequently the preparation of the anionic...
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Fall 2015
Natural-gas fuelled catalytic heaters are commonly used in heating industrial space and remote location operations. Industrial units typically contain platinum that provides methane combustion at lower temperatures than non-catalytic burning. This work aimed to find a cost-efficient alternative...
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Fall 2017
Increasingly stringent environmental regulations for the sulfur content in fuels pose significant technological challenges for refineries. Current single-stage hydrodesulfurization (HDS) technologies are not efficient enough to achieve ultra-deep levels of sulfur, 10 ppmw S for transportation,...