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Spring 2015
Supramolecular rosette nanotubes (RNTs) are obtained by the hierarchical self-assembly of mono and twin G^C building blocks. The mono G^C motif is a fused bicyclic ring of guanine and cytosine with six self-complementary sets of hydrogen bonding sites, while the twin G^C motif is a covalently...
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Fall 2013
Rosette nanotubes (RNTs) are bio-inspired nanomaterials generated from the self-assembly of a guanine-cytosine motif called the “G∧C” base. These nanotubular architectures are promising 2-D coating materials for bone tissue engineering applications, and delivery scaffolds for hydrophobic drug...
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Tuning π-Conjugated Polymers with Heteroatoms: Synthesis of Polytellurophenes and Soluble Polyacetylenes
DownloadFall 2021
This Thesis describes the synthesis and investigation of π-conjugated oligomers and polymers with optoelectronic properties affected by the presence of a heteroatom. Two major classes of polymers are discussed: 1) polytellurophenes, where the backbone is formed by 5-membered heterocycles...