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Skip to Search Results- 33Mass-spectrometry
- 24Chemistry
- 23Organic compounds. Synthesis.
- 22Metabolomics
- 21Capillary electrophoresis.
- 21Catalysis
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Spring 2010
The first chapter of this thesis represents the continued development of a general method for the formation of benzo-fused N-heterocycles by formal radical cyclization onto benzene rings. Important stages in this process involve 1) the copper-mediated coupling of various amino alcohols to...
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Fall 2009
In an attempt to expand the scope of titanacyclobutenes, malonate-derived α,ω-alkylpropargyl dibromides and α,ω-bis(bromopropargyl) malonates were prepared and examined for their reactivity with titanocene reagents. Unfortunately, all of the α,ω-alkylpropargyl dibromomalonates failed, presumably...
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Synthesis of boracyclobutenes by transmetallation; insertion and demetallation reactions of boracyclobutenes and titanacyclobutene complexes
DownloadFall 2009
A series of new titanacyclobutene complexes were prepared by samarium diiodide-mediated central carbon alkylation of η³-propargyltitanium complexes. The titanacyclobutenes were synthesized in high yield and completely characterized using NMR spectroscopy and, where applicable, single crystal...
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Spring 2017
Bradyrhizose, a bicyclic monosaccharide, was reported in 2011 by Molinaro and coworkers at the University of Naples in Italy. This unusual carbohydrate was isolated from the lipopolysaccharide (LPS) of Bradyrhizobium sp. BTAi1 and sp. ORS278 as the only component of the O-antigen. These...
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Spring 2020
“To understand something” is a perpetual theme in scientific research. In carbohydrate chemistry, we pursue to understand certain properties of sugar molecules. This is further described as the purpose of my research “understanding Mycobacterium marinum lipooligosaccharides’ (LOSs) immnuogenic...