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- 1Bicyclization
- 1Cobalt-mediated
- 1Cycloaddition
- 1Decomplexation
- 1Density functional theory
- 1Hapticity
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Spring 2010
A new method for the preparation of seven-membered carbocycles via cobalt-mediated [5+2] cycloaddition methodology is presented. We have demonstrated that CpCo(η5-pentadienyl)+ systems undergo cycloaddition reactions with alkynes in a diastereocontrolled and high-yielding process. When...
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