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Development of dynamic column breakthrough for multicomponent adsorption equilibrium and diffusion
DownloadFall 2022
Pressure and temperature swing adsorption processes are increasingly being designed and optimized computationally. The reliability of these predictions are highly dependent on the quality of the experimental equilibrium and kinetic data used in these simulations. Consistent experimental...
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Effect of adsorbate’s polarity, steric hindrance, aromaticity, and boiling point on competitive adsorption in a multi-staged countercurrent fluidized bed reactor using activated carbon and zeolite
DownloadFall 2022
Understanding the multi-component adsorption of volatile organic compounds (VOCs) is of essential importance for real-world engineering applications. Various properties of VOCs can affect their competitive adsorption when there is a mixture of these compounds in the process stream. This thesis...
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Effect of Desorption Purge Gas Oxygen Impurity on Heel Formation During Regeneration of Beaded Activated Carbon Saturated with Organic Vapors
DownloadFall 2017
Irreversible adsorption or heel formation during cyclic adsorption/regeneration of high molecular weight volatile organic compounds (VOCs) onto activated carbon decreases its adsorption capacity and lifetime. The effect of regeneration purge gas oxygen impurity on activated carbon performance,...
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Effect of Heat Exchanger Volume and Geometry on Power Output of a Low Temperature Difference Stirling Engine
DownloadFall 2022
This work presents the results of an investigation into heat exchanger design for low temperature difference Stirling engines (LTDSEs). The aim of this study was to determine if there is an optimum heat exchanger geometry for producing maximum power output for a LTDSE. There are multiple factors...
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Effect of Purge Gas Flow Rate and Oxygen Impurity on Heel build-up and Prediction of Heel build-up Using Machine Learning
DownloadFall 2021
Heel buildup, i.e., the accumulation of non-desorbed/non-desorbable adsorbates and their by-products on an adsorbent, during cyclic adsorption/regeneration of volatile organic compounds (VOCs) onto activated carbon decreases its adsorption capacity and lifetime. In this this study, the effect of...
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Effect of Surface Oxygen Groups on Irreversible Adsorption of Volatile Organic Compounds on Beaded Activated Carbon
DownloadSpring 2017
Adsorption by activated carbons is a widely used method for controlling emission of volatile organic compounds (VOCs). However, accumulation of adsorbates and/or regeneration by-products (heel buildup) during cyclic process is a common challenge in this process. Irreversible adsorption restricts...
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Effects of Adsorbate Properties on Heel Buildup on Activated Carbon Fiber Cloth during Electrothermal Regeneration
DownloadSpring 2017
Automotive painting booths are a major source of volatile organic compounds’ (VOCs) in the automotive manufacturing sector. Adsorption on activated carbon (AC) has been widely used as a low cost and energy efficient VOC control method. A major challenge associated with the cyclic...
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Spring 2015
Separation of ethane and heavier hydrocarbons from natural gas stream is a major topic in petrochemical industry due to the increase in Natural gas reserves in North America. Natural gas liquids are frequently separated using a cryogenic distillation process, which is able to separate all the C3+...
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Exploring Atomic Force Microscopy To Probe Charge Transport Through Molecular Films And For The Development Of Combinatorial Force Microscopy
DownloadFall 2012
Since the invention of the atomic force microscope (AFM), this technology has had profound implications in the study of material science and molecular biology. The ability to visualize and perform quantitative analysis of the nanoscale properties of surfaces has provided great insights into...
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Spring 2018
Due to the natural heterogeneity of rock there exists a large variance between samples in geomechanical engineering testing. Additionally, the number of samples available for testing that meet the screening requirements for grain size, mineralogy, bedding orientation and moisture content can...