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Fall 2015
2015 marks the 50th anniversary of Moore's law, which has described the exponential progress in semiconductor patterning technologies, enabling creation of smaller circuitry features at greater densities. These continued hardware developments, economically mass manufactured, have made possible...
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Fall 2019
A novel nopoldiol-benzoxaborolate cross-link formed by a bioorthogonal click reaction between nopoldiol- and benzoxaborole-based components was developed for the preparation of biomaterials such as hydrogels and nanogels. In contrast to the traditional boronic ester-based cross-links, this...
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Fall 2017
The development of photolithography has been the main driving force of the semiconductor industry to keep pace with Moore’s Law for over five decades. The theoretical resolution limit of state-of-the-art 193 nm photolithography is about 36 nm (half pitch). By integrating multiple patterning...
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Spring 2022
Molecular self-assembly is the basis of structure in Nature. While of far less complexity than a natural system, the same physical rules apply to simple synthetic designed systems that spontaneously form self-assembled structures and patterns. The self-assembly of block copolymers (BCPs) is an...
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Tuning π-Conjugated Polymers with Heteroatoms: Synthesis of Polytellurophenes and Soluble Polyacetylenes
DownloadFall 2021
This Thesis describes the synthesis and investigation of π-conjugated oligomers and polymers with optoelectronic properties affected by the presence of a heteroatom. Two major classes of polymers are discussed: 1) polytellurophenes, where the backbone is formed by 5-membered heterocycles...